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Guncotton

 

Guncotton, or nitrocellulose (also known as trinitrocellulose and cellulose nitrate) is a mild explosive, used in rockets, propellants, printing ink bases, leather finishing, and celluloid (a mixture of nitrocellulose and camphor; first used to manufacture billiard balls).  It is prepared by treating ordinary cotton with a mixture of concentrated nitric and sulfuric acids, which replaces the hydrogen atom on the OH groups in the cellulose polymers with nitro [NO2] groups:

This has the effect of "planting" oxygen deep within the cotton fibers, making it much easier to burn.  (Chemically, nitrocellulose is similar to nitroglycerin and trinitrotoluene [TNT], which also contain nitro groups).

Once all of the acids have been rinsed off, and the guncotton is allowed to dry completely, applying a small flame, heat, or a spark will set guncotton off, producing a flash of orange flame.  Almost all of the cotton is converted to gaseous products, including carbon dioxide, carbon monoxide, water vapor, and nitrogen gas.

 

In the following demonstrations, guncotton has been prepared by overnight treatment of cotton in concentrated nitric and sulfuric acids, following by thorough rinsing and 24 hours of drying.  In the first film clip, a ball of guncotton is ignited, resulting in a flash of flame and a nice "poof" sound effect.  (Notice that nothing remains of the original cotton ball; an untreated cotton ball would leave a lot of ash and unburned residue.)  In the second film clip, a continuous line of guncotton has been fastened to a meter stick with double-stick tape; when it is ignited at one end it takes less than three seconds for the roaring flame to travel to the other end.  (The bumps on the meter stick when the demo is finished are the pieces of tape I used to fasten the guncotton.)

 

 

Since the guncotton flames up so quickly, I have found that the safest way to light it is with a butane lighter stick, which gives you some distance between the point of ignition and your hands.  Another safe method of ignition is to heat up the end of a pair of tongs or a glass stirring rod in a Bunsen burner flame, and then touch the hot end to the guncotton.  An ordinary kitchen match or a spark from a striker will also work, but I've found that I usually end up burning the hair off my fingers when I do it that way.

Once it has dried out, the guncotton will stay good for at least a couple of months.  I don't like to leave unexploded guncotton lying around, since it ignites so easily, but if I'm going to use it soon I usually store it wrapped in aluminum foil, or in a plastic bottle covered with saran-wrap or foil.

Guncotton can also be stored stored under water, where it will be safe from accidental ignition, and will stay good indefinitely.

 

Video Clip 1:  REAL, 451 KB

 

 

Video Clip 2:  REAL, 558 KB

 

 

!!!  Hazards  !!!

Concentrated nitric and sulfuric acids are extremely dangerous materials; handle with care!

The mixing of nitric and sulfuric acids is a very exothermic process.  The nitric acid should be added to the sulfuric acid slowly, with cooling in an ice bath.

 

 

Procedures

Combustion of Cellulose Nitrate (Guncotton):  Bassam Z. Shakhashiri, Chemical Demonstrations: A Handbook for Teachers of Chemistry, Volume 1.  Madison: The University of Wisconsin Press, 1983, p. 43-45.

Nitrocellulose:  Lee R. Summerlin, Christie L. Borgford, and Julie B. Ealy, Chemical Demonstrations:  A Sourcebook for Teachers, Volume 2, 2nd ed.  Washington, D.C.:  American Chemical Society, 1988, p. 105-106.

 

 

References

Richard J. Lewis, Sr., Hawley's Condensed Chemical Dictionary, 13th ed.  New York:  Van Nostrand Reinhold, 1997.

Martha Windholz (ed.), The Merck Index, 10th ed. Rahway: Merck & Co., Inc., 1983.